In October 1985, Diana, Princess of Wales and Prince Charles, Prince of Wales sat with Alastair Burnet in Kensington Palace for a lengthy and intimate interview covering a wide range of subjects. The resultant programme was released under the title The Prince and Princess of Wales Talking Personally With Alastair Burnet. Opening with a photoshoot with three-year-old Prince William and one-year-old Prince Harry, the programme includes many insights into the personalities of the Prince and Princess of Wales and the relationship between them five years into their marriage.

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