Jennifer Aniston FINALLY EXPOSES How Angelina Jolie RUINED Her Relationship with Brad Pitt .Back in the early 2000s, Brad Pitt and Jennifer Aniston were the ultimate Hollywood power couple. But that all changed in 2005 when Brad met Angelina Jolie on the set of "Mr. and Mrs. Smith." That meet-up kicked off a major romance that broke up his marriage with Jennifer, causing a media storm and grabbing everyone's attention. The drama didn't stop there—Brad's later marriage and messy split from Angelina kept them in the headlines and had folks everywhere hooked. #jenniferaniston #bradpitt #angelinajolie #jenniferanistonbradpitt #angelinajoliebradpitt #bradpittchildren #angelinajoliechildren #bradpittangelinajoliejenniferaniston #bradpittangelinajolielawsuit